The Chemistry of Organomagnesium Compounds (eBook, PDF)

Redaktion: Rappoport, Zvi; Marek, Ilan

• Format: PDF

Produktbeschreibung

Magnesium remains almost unique among the metals in its ability to react directly with a wide variety of compounds. This organic chemistry field has seen steady progress, and a volume on this topic is long overdue. In the tradition of the Patai Series this title treats all aspects of functional groups, containing chapters on the theoretical and computational foundations; on analytical and spectroscopic aspects with dedicated chapters on Mass Spectrometry, NMR, IR/UV, etc.; on reaction mechanisms; on applications in syntheses. Depending on the functional group there are also chapters on industrial use, on effects in biological and/or environmental systems. Since the area of Organomagnesium Chemistry continues to grow far beyond the classical Grignard Reagents, this is an essential resource to help the reader keep abreast of the latest developments.

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Produktdetails

• Verlag: John Wiley & Sons
• Seitenzahl: 920
• Erscheinungstermin: 30. April 2008
• Englisch
• ISBN-13: 9780470751862
• Artikelnr.: 37299155

Autorenporträt

Professor Zvi Rappoport, Department of Organic Chemistry, The Hebrew University of Jerusalem, Jerusalem, Israel. Ilan Marek is Professor of Chemistry at the Technion - Israel Institute of Technology. He was educated in France and received his PhD thesis in 1988 from the University Pierre et Marie Curie, Paris. He has been visiting Professor at the University de Montreal (Canada); University of Strasbourg (France); University Paris-Descartes (France); California Institute of Technology (USA) and at the Ecole Nationale Superieure de Chimie de Montpellier (France). He was a member of the International Scientific Committee of the European Symposium on Organic Chemistry (ESOC), including the position of Chairman (2007-2009) and is currently the chairman of the division of organic chemistry, European Association of Chemical and Molecular Sciences (EuCheMS).

Inhaltsangabe

1. Structural organomagnesium chemistry (Johann T.B.H. Jastrzebski, Jaap
Boersma and Gerard van Koten).
2. The thermochemistry of organomagnesium compounds (Joel F. Liebman,
Torkil Holm and Suzanne W. Slayden).
3. NMR of organomagnesium compounds (Peter J. Heard).
4. Formation, chemistry and structure of organomagnesium species in
solvent-free environments (Richard A. J. O'Hair).
5. Photochemical transformations involving magnesium porphyrins and
phthalocyanines (Natalia N. Sergeeva and Mathias O. Senge).
6. Electrochemistry of organomagnesium compounds (Jan S. Jaworski).
7. Analytical aspects of organomagnesium compounds (Jacob Zabicky).
8. Biochemistry of magnesium (James Weston).
9. Theoretical studies of the addition of RMgX to carbonyl compounds
(Shinichi Yamabe and Shoko Yamazaki).
10. Organomagnesium-group 15-and Organomagnesium-group 16-bonded complexes
(Katherine L. Hull and Kenneth W. Henderson).
11. Preparation and reactivity of Magnesium enolates (Claude Grison).
12. Functionalized organomagnesium compounds: Synthesis and reactivity
(Paul Knochel, Andrey Gavryushin and Katja Brade).
13. Iron-Catalyzed reactions of Grignard Reagents (Gérard Cahiez and
Christophe Duplais).
14. Carbomagnesiation reactions (Kenichiro Itami and Jun-ichi Yoshida).
15. The chemistry of organomagnesium ate complexes (Hideki Yorimitsu and
Koichiro Oshima).
16. The chemistry of magnesium carbenoids (Tsuyoshi Satoh).
17. Catalytic enantioselective conjugate addition and allylic alkylation
reactions using Grignard reagents (Fernando López, Adriaan J. Minnaard and
Ben L. Feringa).
Author Index.
Subject Index.

Rezensionen

"This book continues the high standard of The Chemistry of Functional Groups series and is an essential resource for professional organic and inorganic chemists and their research groups who have an interest in organometallic chemistry. It could also prove useful in postgraduate teaching for designing a modern course on the subject. With the recent report of the first crystallographically characterized Mg Mg bonded compound, this area is likely to increase in popularity and research activity; thus, the publication of this book is timely. A copy should be made available in every library that houses a section on advanced chemistry at the postgraduate level and above." ( Journal of the American Chemical Society , November 12, 2008)