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Beginning of the millennium is characterized by an enormous economic and scientific interest on the development of new materials (advanced materials) with special properties, inconceivable in the case of classical materials. To the category of these new materials belong also metallic alloys with metastabile structures (amorphous, quasicrystalline, nanocrystalline), which through a series of mechanical, physical and chemical properties, are required in technical fields peak. The paper Amorphous and nanocrystalline alloys represents a summary of studies and investigations realized by collective researchers from country and abroad in amorphous and nanocrystalline metallic alloys, approaching problems about the new materials structure and about the thermodynamic and formation kinetic of amorphous and nanocrystalline structures.