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The present wok highlights the synthesis and biological activities associated with the heterocyclic compounds having 1, 2, 4 Thiadiazole and 1, 2, 4 Dithiazole moieties and consists of the various synthetic strategies adopted in the synthesis of 1, 2, 4 Thiadiazole and 1, 2, 4 Dithiazole derivatives from the corresponding thiobiurets and dithiobiurets respectively including a bird s eye view of their different biological applications.