This book provides a modern account of research on liquid-liquid interfaces, with particular emphasis on charge transfer effects. It discusses their applications in biotechnology such as drug delivery, mineral extraction processes, and the manufacture of biosensors.
This book provides a modern account of research on liquid-liquid interfaces, with particular emphasis on charge transfer effects. It discusses their applications in biotechnology such as drug delivery, mineral extraction processes, and the manufacture of biosensors.
1. Equilibrium electric potential between two immiscible electrolyte solutions /T. Kakiuchi I. Distribution potential A. Phase boundary potential B. Distribution potential at ITIES 1. Nernst equation 2. Standard ion transfer potential 3. Calculation of distribution potential 4. Distribution potential in the presence of ion pair formation and complex formation reactions 5. Distribution of potential 6. Distribution potential in small systems II. Polarizability of the liquid liquid interface III. Nonpolarized ITIES and reference potentials in organic phases IV. Free energy of coupling of ion transfer and electron transfer 1. Mixed potential determined by electron transfer and ion transfer at ITIES 2. Partition of indifferent electrolyte ions 3. Relative strength of ion transfer and electron transfer V. Conclusions VI. References 2. Volta and surface potentials at liquid /liquid interfaces /Z. Koczorowski I. Introduction II. Electrified liquid /liquid interfaces and their electrical potentials III. Volta potential and voltaic cells IV. Voltaic cells with water /nonpolar liquid interfaces V. Voltaic cells with immiscible electrolyte solution interface VI. Experimental methods of investigation of voltaic cells VII. Final remarks VIII. References 3. Ion solvation /Y. Marcus I. Introduction II. The relevant properties of ions III. The relevant properties of solvents IV. Quantities describing ionic hydration A. Thermodynamics of ion hydration B. Methods of investigation C. Other properties relevant to ion hydration D. The data E. Interpretation V. Transfer of ions into non aqueous solvents A. Methods of investigation B. The data C. Interpretation VI. Preferential ion solvation in mixed solvents VII. References 4. Adsorption isotherms and the structure of oil /water interface /V. S. Markin and A. G. Volkov I. Introduction II. Surface solution
1. Equilibrium electric potential between two immiscible electrolyte solutions /T. Kakiuchi I. Distribution potential A. Phase boundary potential B. Distribution potential at ITIES 1. Nernst equation 2. Standard ion transfer potential 3. Calculation of distribution potential 4. Distribution potential in the presence of ion pair formation and complex formation reactions 5. Distribution of potential 6. Distribution potential in small systems II. Polarizability of the liquid liquid interface III. Nonpolarized ITIES and reference potentials in organic phases IV. Free energy of coupling of ion transfer and electron transfer 1. Mixed potential determined by electron transfer and ion transfer at ITIES 2. Partition of indifferent electrolyte ions 3. Relative strength of ion transfer and electron transfer V. Conclusions VI. References 2. Volta and surface potentials at liquid /liquid interfaces /Z. Koczorowski I. Introduction II. Electrified liquid /liquid interfaces and their electrical potentials III. Volta potential and voltaic cells IV. Voltaic cells with water /nonpolar liquid interfaces V. Voltaic cells with immiscible electrolyte solution interface VI. Experimental methods of investigation of voltaic cells VII. Final remarks VIII. References 3. Ion solvation /Y. Marcus I. Introduction II. The relevant properties of ions III. The relevant properties of solvents IV. Quantities describing ionic hydration A. Thermodynamics of ion hydration B. Methods of investigation C. Other properties relevant to ion hydration D. The data E. Interpretation V. Transfer of ions into non aqueous solvents A. Methods of investigation B. The data C. Interpretation VI. Preferential ion solvation in mixed solvents VII. References 4. Adsorption isotherms and the structure of oil /water interface /V. S. Markin and A. G. Volkov I. Introduction II. Surface solution
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