Sabu Thomas, Daniel Grande, Uros Cvelbar, K V S N Raju, Ramanuj Narayan, Selvin P Thomas, Akhina H
Micro- And Nano-Structured Interpenetrating Polymer Networks
From Design to Applications
Sabu Thomas, Daniel Grande, Uros Cvelbar, K V S N Raju, Ramanuj Narayan, Selvin P Thomas, Akhina H
Micro- And Nano-Structured Interpenetrating Polymer Networks
From Design to Applications
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This book examines the current state of the art, new challenges, opportunities, and applications of IPNs. With contributions from experts across the globe, this survey is an outstanding resource reference for anyone involved in the field of polymer materials design for advanced technologies. * Comprehensively summarizes many of the recent technical research accomplishments in the area of micro and nanostructured Interpenetrating Polymer Networks * Discusses various aspects of synthesis, characterization, structure, morphology, modelling, properties, and applications of IPNs * Describes how…mehr
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This book examines the current state of the art, new challenges, opportunities, and applications of IPNs. With contributions from experts across the globe, this survey is an outstanding resource reference for anyone involved in the field of polymer materials design for advanced technologies. * Comprehensively summarizes many of the recent technical research accomplishments in the area of micro and nanostructured Interpenetrating Polymer Networks * Discusses various aspects of synthesis, characterization, structure, morphology, modelling, properties, and applications of IPNs * Describes how nano-structured IPNs correlate their multiscale structure to their properties and morphologies * Serves as a one-stop reference resource for important research accomplishments in the area of IPNs and nano-structured polymer systems * Includes chapters from leading researchers in the IPN field from industry, academy, government and private research institutions
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Produktdetails
- Produktdetails
- Verlag: John Wiley & Sons / Wiley
- Seitenzahl: 432
- Erscheinungstermin: 11. April 2016
- Englisch
- Abmessung: 236mm x 152mm x 28mm
- Gewicht: 771g
- ISBN-13: 9781118138175
- ISBN-10: 1118138171
- Artikelnr.: 43043675
- Verlag: John Wiley & Sons / Wiley
- Seitenzahl: 432
- Erscheinungstermin: 11. April 2016
- Englisch
- Abmessung: 236mm x 152mm x 28mm
- Gewicht: 771g
- ISBN-13: 9781118138175
- ISBN-10: 1118138171
- Artikelnr.: 43043675
Prof. Dr. Sabu Thomas teaches at Mahatma Gandhi University's School of Chemical Sciences and International and Inter University Centre for Nanoscience and Nanotechnology. Dr. Daniel Grande is a CNRS senior researcher based at the East-Paris Institute of Chemistry and Materials Science belonging to both CNRS and the "Université Paris-Est Créteil." Dr. Uros Cvelbar is a researcher at Slovenia's Jozef Stefan Institute. Dr. K.V.S.N. Raju and Dr. Ramanuj Narayan are scientists working with the Indian Institute of Chemical Technology's Polymers and Functional Materials Division. Dr. Selvin P. Thomas iis an assistant professor in Chemical Engineering in the Yanbu Research Center of the Royal Commission for Yanbu Colleges and Institutes (RCYCI). Akhina H is a senior research fellow(CSIR) at International and Inter University Centre for Nanoscience and Nanotechnology at Mahatma Gandhi University.
List of Contributors xiii 1 Micro- and Nano-structured Interpenetrating
Polymer Networks: State of the Art, New Challenges, and Opportunities 1
Jose James, George V. Thomas, Akhina H. and Sabu Thomas 1.1 Introduction 1
1.2 Types of Interpenetrating Polymer Networks 2 1.3 Synthesis of
Interpenetrating Polymer Networks 5 1.4 Characterization of
Interpenetrating Polymer Networks 8 1.5 Applications of Interpenetrating
Polymer Networks 23 1.6 Future Trends 23 Acknowledgement 25 References 25 2
Miscibility, Morphology, and Phase Behavior of IPNs 29 Xuemei Wu, Gaohong
He, Xiaoming Yan, Xiangcun Li, Wu Xiao and Xiaobin Jiang 2.1 Introduction
29 2.2 Miscibility of Interpenetrating Polymer Networks 30 2.3 Phase
Diagram 35 2.4 Morphology of Interpenetrating Polymer Networks 43
Acknowledgments 62 References 62 3 Synthetic Rubber-Based IPNs 69 Qihua
Wang, Shoubing Chen and Tingmei Wang 3.1 Introduction 69 3.2 Synthetic
Rubber-Based IPNs 71 3.3 Summary and Conclusions 101 Acknowledgments 102
References 102 4 Micro- and Nanostructured IPNs Based on Thermosetting
Resins 109 Sanja Marinovic, Ivanka Popovic and Branko Dunjic 4.1
Introduction 109 4.2 Experimental Details 110 4.3 Influence of HBP(A)
Contents in IPNs on IPN Mechanical Properties 115 4.4 Influence of Reactive
Diluent in Interpenetrating Polymer Networks on their Properties 119 4.5
Conclusions 124 Acknowledgment 125 References 125 5 Macro-, Meso-, and
Nanoporous Systems Designed from IPNs 127 Daniel Grande 5.1 Introduction
127 5.2 Porous Systems Derived from Semi-Interpenetrating Polymer Networks
130 5.3 (Nano)Porous Systems Derived from Interpenetrating Polymer Networks
135 5.4 Conclusions 139 Acknowledgments 140 References 140 6 Natural
Rubber-Based Micro- and Nanostructured IPNs 145 Sa-Ad Riyajan 6.1
Introduction 145 6.2 Natural Rubber 146 6.3 Synthesis of Polymer IPN 148
6.4 Properties of IPN Made from NR and Plastics 155 6.5 Conclusions 174
Acknowledgments 174 References 174 7 The Synthesis and the Applications of
IPNs Based on Smart Polymers 179 Guillermina Burillo, Emilio Bucio and
Lorena Garcia-Uriostegui 7.1 Introduction 179 7.2 Stimuli-Responsive
Polymers 180 7.3 Interpenetrating Polymer Networks and
Semi-Interpenetrating Networks 181 7.4 The Synthesis and the Applications
of Semi-Interpenetrating Networks and Interpenetrating Networks 181 7.5
Interpenetrating Polymer Networks 184 7.6 Interpenetrating Polymer Networks
and Semi-Interpenetrating Networks Synthesized by Ionizing Radiation 186
7.7 Semi-Interpenetrating Networks and Interpenetrating Networks in the
Heavy Ions Immobilization 188 7.8 The Novel Architectures of IPNs Developed
by Ionizing Radiation Polymerization 189 7.9 Conclusions 192
Acknowledgments 192 References 193 8 Microscopy of IPNs 199 Rameshwar
Adhikari 8.1 Introduction and Overview 199 8.2 Sample Preparation
Techniques for Microscopic Analysis 200 8.3 Microscopy of Interpenetrating
Polymer Networks: An Overview 202 8.4 Morphological Characterization of
Polymer Networks 206 8.5 Concluding Notes 220 Acknowledgments 220
References 220 9 Viscoelastic Properties of Interpenetrating Polymer
Networks 229 Sudipta Goswami 9.1 Introduction 229 9.2 Viscoelastic
Properties of Simultaneous IPNs 234 9.3 Viscoelastic Properties of
Sequential IPNs 241 9.4 Overall Summary and Future Scope 252 9.5 Conclusion
255 References 256 10 Interpenetrating and Semi-Interpenetrating Polymer
Networks of Polyurethane 259 Chepuri R.K. Rao, Ramanuj Narayan and K.V.S.N.
Raju 10.1 Introduction 259 References 278 11 Solid-State NMR and ESR
Studies of IPNs 283 Srecko Valic, Mladen Andreis and Damir Klepac 11.1
Introduction 283 11.2 Theoretical Background 284 11.3 Nuclear Magnetic
Resonance of Interpenetrating Polymer Networks and Semi-Interpenetrating
Polymer Networks 290 11.4 Electron Spin Resonance Studies of
Interpenetrating Polymer Networks and Semi-Interpenetrating Polymer
Networks 302 11.5 Conclusion 313 References 313 12 Diffusion, Transport,
and Barrier Properties of IPNs 319 Runcy Wilson, S. Anil Kumar, Miran
Mozeti , Uros Cvelbar and Sabu Thomas 12.1 Introduction 319 12.2 Background
of Interpenetrating Polymer Networks 320 12.3 Transport Properties:
Theoretical and Practical Aspects 321 12.4 Transport Mechanism 324 12.5
Sorption and Diffusion of Solvents 326 12.6 Gas Barrier Properties of
Interpenetrating Polymer Networks 331 12.7 Pervaporation Characteristics of
Interpenetrating Polymer Networks 332 12.8 Principles of Pervaporation 333
12.9 Vapor Sorption 334 12.10 Conclusion 335 12.11 Applications,
Challenges, Difficulties, and Future Directions 335 References 336 13 Aging
of Interpenetrating Polymer Networks 341 Selvin P. Thomas and Mohammed N.
Alghamdi 13.1 Introduction 341 13.2 Aging of Interpenetrating Polymer
Networks 342 13.3 Conclusion 361 References 362 14 Theoretical Modeling and
Simulation of IPNs 365 Prathab Baskar 14.1 Introduction 365 14.2
Theoretical Simulations 366 14.3 Molecular Dynamics Methods and Theory 368
14.4 Molecular Dynamic Study of Surface/Interface Properties of
Thermoplastic Apparent Interpenetrating Polymer Networks and
Organic-Inorganic Composite Interpenetrating Polymer Networks 375 14.5
Conclusions 380 References 380 15 Applications of Interpenetrating Polymer
Networks 383 Radhika Raveendran and Chandra P. Sharma 15.1 Introduction 383
15.2 What are Interpenetrating Polymer Networks? 384 15.3 Properties of
Interpenetrating Polymer Networks 385 15.4 Applications of Interpenetrating
Polymer Networks 385 15.5 Conclusion 393 References 394 Index 399
Polymer Networks: State of the Art, New Challenges, and Opportunities 1
Jose James, George V. Thomas, Akhina H. and Sabu Thomas 1.1 Introduction 1
1.2 Types of Interpenetrating Polymer Networks 2 1.3 Synthesis of
Interpenetrating Polymer Networks 5 1.4 Characterization of
Interpenetrating Polymer Networks 8 1.5 Applications of Interpenetrating
Polymer Networks 23 1.6 Future Trends 23 Acknowledgement 25 References 25 2
Miscibility, Morphology, and Phase Behavior of IPNs 29 Xuemei Wu, Gaohong
He, Xiaoming Yan, Xiangcun Li, Wu Xiao and Xiaobin Jiang 2.1 Introduction
29 2.2 Miscibility of Interpenetrating Polymer Networks 30 2.3 Phase
Diagram 35 2.4 Morphology of Interpenetrating Polymer Networks 43
Acknowledgments 62 References 62 3 Synthetic Rubber-Based IPNs 69 Qihua
Wang, Shoubing Chen and Tingmei Wang 3.1 Introduction 69 3.2 Synthetic
Rubber-Based IPNs 71 3.3 Summary and Conclusions 101 Acknowledgments 102
References 102 4 Micro- and Nanostructured IPNs Based on Thermosetting
Resins 109 Sanja Marinovic, Ivanka Popovic and Branko Dunjic 4.1
Introduction 109 4.2 Experimental Details 110 4.3 Influence of HBP(A)
Contents in IPNs on IPN Mechanical Properties 115 4.4 Influence of Reactive
Diluent in Interpenetrating Polymer Networks on their Properties 119 4.5
Conclusions 124 Acknowledgment 125 References 125 5 Macro-, Meso-, and
Nanoporous Systems Designed from IPNs 127 Daniel Grande 5.1 Introduction
127 5.2 Porous Systems Derived from Semi-Interpenetrating Polymer Networks
130 5.3 (Nano)Porous Systems Derived from Interpenetrating Polymer Networks
135 5.4 Conclusions 139 Acknowledgments 140 References 140 6 Natural
Rubber-Based Micro- and Nanostructured IPNs 145 Sa-Ad Riyajan 6.1
Introduction 145 6.2 Natural Rubber 146 6.3 Synthesis of Polymer IPN 148
6.4 Properties of IPN Made from NR and Plastics 155 6.5 Conclusions 174
Acknowledgments 174 References 174 7 The Synthesis and the Applications of
IPNs Based on Smart Polymers 179 Guillermina Burillo, Emilio Bucio and
Lorena Garcia-Uriostegui 7.1 Introduction 179 7.2 Stimuli-Responsive
Polymers 180 7.3 Interpenetrating Polymer Networks and
Semi-Interpenetrating Networks 181 7.4 The Synthesis and the Applications
of Semi-Interpenetrating Networks and Interpenetrating Networks 181 7.5
Interpenetrating Polymer Networks 184 7.6 Interpenetrating Polymer Networks
and Semi-Interpenetrating Networks Synthesized by Ionizing Radiation 186
7.7 Semi-Interpenetrating Networks and Interpenetrating Networks in the
Heavy Ions Immobilization 188 7.8 The Novel Architectures of IPNs Developed
by Ionizing Radiation Polymerization 189 7.9 Conclusions 192
Acknowledgments 192 References 193 8 Microscopy of IPNs 199 Rameshwar
Adhikari 8.1 Introduction and Overview 199 8.2 Sample Preparation
Techniques for Microscopic Analysis 200 8.3 Microscopy of Interpenetrating
Polymer Networks: An Overview 202 8.4 Morphological Characterization of
Polymer Networks 206 8.5 Concluding Notes 220 Acknowledgments 220
References 220 9 Viscoelastic Properties of Interpenetrating Polymer
Networks 229 Sudipta Goswami 9.1 Introduction 229 9.2 Viscoelastic
Properties of Simultaneous IPNs 234 9.3 Viscoelastic Properties of
Sequential IPNs 241 9.4 Overall Summary and Future Scope 252 9.5 Conclusion
255 References 256 10 Interpenetrating and Semi-Interpenetrating Polymer
Networks of Polyurethane 259 Chepuri R.K. Rao, Ramanuj Narayan and K.V.S.N.
Raju 10.1 Introduction 259 References 278 11 Solid-State NMR and ESR
Studies of IPNs 283 Srecko Valic, Mladen Andreis and Damir Klepac 11.1
Introduction 283 11.2 Theoretical Background 284 11.3 Nuclear Magnetic
Resonance of Interpenetrating Polymer Networks and Semi-Interpenetrating
Polymer Networks 290 11.4 Electron Spin Resonance Studies of
Interpenetrating Polymer Networks and Semi-Interpenetrating Polymer
Networks 302 11.5 Conclusion 313 References 313 12 Diffusion, Transport,
and Barrier Properties of IPNs 319 Runcy Wilson, S. Anil Kumar, Miran
Mozeti , Uros Cvelbar and Sabu Thomas 12.1 Introduction 319 12.2 Background
of Interpenetrating Polymer Networks 320 12.3 Transport Properties:
Theoretical and Practical Aspects 321 12.4 Transport Mechanism 324 12.5
Sorption and Diffusion of Solvents 326 12.6 Gas Barrier Properties of
Interpenetrating Polymer Networks 331 12.7 Pervaporation Characteristics of
Interpenetrating Polymer Networks 332 12.8 Principles of Pervaporation 333
12.9 Vapor Sorption 334 12.10 Conclusion 335 12.11 Applications,
Challenges, Difficulties, and Future Directions 335 References 336 13 Aging
of Interpenetrating Polymer Networks 341 Selvin P. Thomas and Mohammed N.
Alghamdi 13.1 Introduction 341 13.2 Aging of Interpenetrating Polymer
Networks 342 13.3 Conclusion 361 References 362 14 Theoretical Modeling and
Simulation of IPNs 365 Prathab Baskar 14.1 Introduction 365 14.2
Theoretical Simulations 366 14.3 Molecular Dynamics Methods and Theory 368
14.4 Molecular Dynamic Study of Surface/Interface Properties of
Thermoplastic Apparent Interpenetrating Polymer Networks and
Organic-Inorganic Composite Interpenetrating Polymer Networks 375 14.5
Conclusions 380 References 380 15 Applications of Interpenetrating Polymer
Networks 383 Radhika Raveendran and Chandra P. Sharma 15.1 Introduction 383
15.2 What are Interpenetrating Polymer Networks? 384 15.3 Properties of
Interpenetrating Polymer Networks 385 15.4 Applications of Interpenetrating
Polymer Networks 385 15.5 Conclusion 393 References 394 Index 399
List of Contributors xiii 1 Micro- and Nano-structured Interpenetrating
Polymer Networks: State of the Art, New Challenges, and Opportunities 1
Jose James, George V. Thomas, Akhina H. and Sabu Thomas 1.1 Introduction 1
1.2 Types of Interpenetrating Polymer Networks 2 1.3 Synthesis of
Interpenetrating Polymer Networks 5 1.4 Characterization of
Interpenetrating Polymer Networks 8 1.5 Applications of Interpenetrating
Polymer Networks 23 1.6 Future Trends 23 Acknowledgement 25 References 25 2
Miscibility, Morphology, and Phase Behavior of IPNs 29 Xuemei Wu, Gaohong
He, Xiaoming Yan, Xiangcun Li, Wu Xiao and Xiaobin Jiang 2.1 Introduction
29 2.2 Miscibility of Interpenetrating Polymer Networks 30 2.3 Phase
Diagram 35 2.4 Morphology of Interpenetrating Polymer Networks 43
Acknowledgments 62 References 62 3 Synthetic Rubber-Based IPNs 69 Qihua
Wang, Shoubing Chen and Tingmei Wang 3.1 Introduction 69 3.2 Synthetic
Rubber-Based IPNs 71 3.3 Summary and Conclusions 101 Acknowledgments 102
References 102 4 Micro- and Nanostructured IPNs Based on Thermosetting
Resins 109 Sanja Marinovic, Ivanka Popovic and Branko Dunjic 4.1
Introduction 109 4.2 Experimental Details 110 4.3 Influence of HBP(A)
Contents in IPNs on IPN Mechanical Properties 115 4.4 Influence of Reactive
Diluent in Interpenetrating Polymer Networks on their Properties 119 4.5
Conclusions 124 Acknowledgment 125 References 125 5 Macro-, Meso-, and
Nanoporous Systems Designed from IPNs 127 Daniel Grande 5.1 Introduction
127 5.2 Porous Systems Derived from Semi-Interpenetrating Polymer Networks
130 5.3 (Nano)Porous Systems Derived from Interpenetrating Polymer Networks
135 5.4 Conclusions 139 Acknowledgments 140 References 140 6 Natural
Rubber-Based Micro- and Nanostructured IPNs 145 Sa-Ad Riyajan 6.1
Introduction 145 6.2 Natural Rubber 146 6.3 Synthesis of Polymer IPN 148
6.4 Properties of IPN Made from NR and Plastics 155 6.5 Conclusions 174
Acknowledgments 174 References 174 7 The Synthesis and the Applications of
IPNs Based on Smart Polymers 179 Guillermina Burillo, Emilio Bucio and
Lorena Garcia-Uriostegui 7.1 Introduction 179 7.2 Stimuli-Responsive
Polymers 180 7.3 Interpenetrating Polymer Networks and
Semi-Interpenetrating Networks 181 7.4 The Synthesis and the Applications
of Semi-Interpenetrating Networks and Interpenetrating Networks 181 7.5
Interpenetrating Polymer Networks 184 7.6 Interpenetrating Polymer Networks
and Semi-Interpenetrating Networks Synthesized by Ionizing Radiation 186
7.7 Semi-Interpenetrating Networks and Interpenetrating Networks in the
Heavy Ions Immobilization 188 7.8 The Novel Architectures of IPNs Developed
by Ionizing Radiation Polymerization 189 7.9 Conclusions 192
Acknowledgments 192 References 193 8 Microscopy of IPNs 199 Rameshwar
Adhikari 8.1 Introduction and Overview 199 8.2 Sample Preparation
Techniques for Microscopic Analysis 200 8.3 Microscopy of Interpenetrating
Polymer Networks: An Overview 202 8.4 Morphological Characterization of
Polymer Networks 206 8.5 Concluding Notes 220 Acknowledgments 220
References 220 9 Viscoelastic Properties of Interpenetrating Polymer
Networks 229 Sudipta Goswami 9.1 Introduction 229 9.2 Viscoelastic
Properties of Simultaneous IPNs 234 9.3 Viscoelastic Properties of
Sequential IPNs 241 9.4 Overall Summary and Future Scope 252 9.5 Conclusion
255 References 256 10 Interpenetrating and Semi-Interpenetrating Polymer
Networks of Polyurethane 259 Chepuri R.K. Rao, Ramanuj Narayan and K.V.S.N.
Raju 10.1 Introduction 259 References 278 11 Solid-State NMR and ESR
Studies of IPNs 283 Srecko Valic, Mladen Andreis and Damir Klepac 11.1
Introduction 283 11.2 Theoretical Background 284 11.3 Nuclear Magnetic
Resonance of Interpenetrating Polymer Networks and Semi-Interpenetrating
Polymer Networks 290 11.4 Electron Spin Resonance Studies of
Interpenetrating Polymer Networks and Semi-Interpenetrating Polymer
Networks 302 11.5 Conclusion 313 References 313 12 Diffusion, Transport,
and Barrier Properties of IPNs 319 Runcy Wilson, S. Anil Kumar, Miran
Mozeti , Uros Cvelbar and Sabu Thomas 12.1 Introduction 319 12.2 Background
of Interpenetrating Polymer Networks 320 12.3 Transport Properties:
Theoretical and Practical Aspects 321 12.4 Transport Mechanism 324 12.5
Sorption and Diffusion of Solvents 326 12.6 Gas Barrier Properties of
Interpenetrating Polymer Networks 331 12.7 Pervaporation Characteristics of
Interpenetrating Polymer Networks 332 12.8 Principles of Pervaporation 333
12.9 Vapor Sorption 334 12.10 Conclusion 335 12.11 Applications,
Challenges, Difficulties, and Future Directions 335 References 336 13 Aging
of Interpenetrating Polymer Networks 341 Selvin P. Thomas and Mohammed N.
Alghamdi 13.1 Introduction 341 13.2 Aging of Interpenetrating Polymer
Networks 342 13.3 Conclusion 361 References 362 14 Theoretical Modeling and
Simulation of IPNs 365 Prathab Baskar 14.1 Introduction 365 14.2
Theoretical Simulations 366 14.3 Molecular Dynamics Methods and Theory 368
14.4 Molecular Dynamic Study of Surface/Interface Properties of
Thermoplastic Apparent Interpenetrating Polymer Networks and
Organic-Inorganic Composite Interpenetrating Polymer Networks 375 14.5
Conclusions 380 References 380 15 Applications of Interpenetrating Polymer
Networks 383 Radhika Raveendran and Chandra P. Sharma 15.1 Introduction 383
15.2 What are Interpenetrating Polymer Networks? 384 15.3 Properties of
Interpenetrating Polymer Networks 385 15.4 Applications of Interpenetrating
Polymer Networks 385 15.5 Conclusion 393 References 394 Index 399
Polymer Networks: State of the Art, New Challenges, and Opportunities 1
Jose James, George V. Thomas, Akhina H. and Sabu Thomas 1.1 Introduction 1
1.2 Types of Interpenetrating Polymer Networks 2 1.3 Synthesis of
Interpenetrating Polymer Networks 5 1.4 Characterization of
Interpenetrating Polymer Networks 8 1.5 Applications of Interpenetrating
Polymer Networks 23 1.6 Future Trends 23 Acknowledgement 25 References 25 2
Miscibility, Morphology, and Phase Behavior of IPNs 29 Xuemei Wu, Gaohong
He, Xiaoming Yan, Xiangcun Li, Wu Xiao and Xiaobin Jiang 2.1 Introduction
29 2.2 Miscibility of Interpenetrating Polymer Networks 30 2.3 Phase
Diagram 35 2.4 Morphology of Interpenetrating Polymer Networks 43
Acknowledgments 62 References 62 3 Synthetic Rubber-Based IPNs 69 Qihua
Wang, Shoubing Chen and Tingmei Wang 3.1 Introduction 69 3.2 Synthetic
Rubber-Based IPNs 71 3.3 Summary and Conclusions 101 Acknowledgments 102
References 102 4 Micro- and Nanostructured IPNs Based on Thermosetting
Resins 109 Sanja Marinovic, Ivanka Popovic and Branko Dunjic 4.1
Introduction 109 4.2 Experimental Details 110 4.3 Influence of HBP(A)
Contents in IPNs on IPN Mechanical Properties 115 4.4 Influence of Reactive
Diluent in Interpenetrating Polymer Networks on their Properties 119 4.5
Conclusions 124 Acknowledgment 125 References 125 5 Macro-, Meso-, and
Nanoporous Systems Designed from IPNs 127 Daniel Grande 5.1 Introduction
127 5.2 Porous Systems Derived from Semi-Interpenetrating Polymer Networks
130 5.3 (Nano)Porous Systems Derived from Interpenetrating Polymer Networks
135 5.4 Conclusions 139 Acknowledgments 140 References 140 6 Natural
Rubber-Based Micro- and Nanostructured IPNs 145 Sa-Ad Riyajan 6.1
Introduction 145 6.2 Natural Rubber 146 6.3 Synthesis of Polymer IPN 148
6.4 Properties of IPN Made from NR and Plastics 155 6.5 Conclusions 174
Acknowledgments 174 References 174 7 The Synthesis and the Applications of
IPNs Based on Smart Polymers 179 Guillermina Burillo, Emilio Bucio and
Lorena Garcia-Uriostegui 7.1 Introduction 179 7.2 Stimuli-Responsive
Polymers 180 7.3 Interpenetrating Polymer Networks and
Semi-Interpenetrating Networks 181 7.4 The Synthesis and the Applications
of Semi-Interpenetrating Networks and Interpenetrating Networks 181 7.5
Interpenetrating Polymer Networks 184 7.6 Interpenetrating Polymer Networks
and Semi-Interpenetrating Networks Synthesized by Ionizing Radiation 186
7.7 Semi-Interpenetrating Networks and Interpenetrating Networks in the
Heavy Ions Immobilization 188 7.8 The Novel Architectures of IPNs Developed
by Ionizing Radiation Polymerization 189 7.9 Conclusions 192
Acknowledgments 192 References 193 8 Microscopy of IPNs 199 Rameshwar
Adhikari 8.1 Introduction and Overview 199 8.2 Sample Preparation
Techniques for Microscopic Analysis 200 8.3 Microscopy of Interpenetrating
Polymer Networks: An Overview 202 8.4 Morphological Characterization of
Polymer Networks 206 8.5 Concluding Notes 220 Acknowledgments 220
References 220 9 Viscoelastic Properties of Interpenetrating Polymer
Networks 229 Sudipta Goswami 9.1 Introduction 229 9.2 Viscoelastic
Properties of Simultaneous IPNs 234 9.3 Viscoelastic Properties of
Sequential IPNs 241 9.4 Overall Summary and Future Scope 252 9.5 Conclusion
255 References 256 10 Interpenetrating and Semi-Interpenetrating Polymer
Networks of Polyurethane 259 Chepuri R.K. Rao, Ramanuj Narayan and K.V.S.N.
Raju 10.1 Introduction 259 References 278 11 Solid-State NMR and ESR
Studies of IPNs 283 Srecko Valic, Mladen Andreis and Damir Klepac 11.1
Introduction 283 11.2 Theoretical Background 284 11.3 Nuclear Magnetic
Resonance of Interpenetrating Polymer Networks and Semi-Interpenetrating
Polymer Networks 290 11.4 Electron Spin Resonance Studies of
Interpenetrating Polymer Networks and Semi-Interpenetrating Polymer
Networks 302 11.5 Conclusion 313 References 313 12 Diffusion, Transport,
and Barrier Properties of IPNs 319 Runcy Wilson, S. Anil Kumar, Miran
Mozeti , Uros Cvelbar and Sabu Thomas 12.1 Introduction 319 12.2 Background
of Interpenetrating Polymer Networks 320 12.3 Transport Properties:
Theoretical and Practical Aspects 321 12.4 Transport Mechanism 324 12.5
Sorption and Diffusion of Solvents 326 12.6 Gas Barrier Properties of
Interpenetrating Polymer Networks 331 12.7 Pervaporation Characteristics of
Interpenetrating Polymer Networks 332 12.8 Principles of Pervaporation 333
12.9 Vapor Sorption 334 12.10 Conclusion 335 12.11 Applications,
Challenges, Difficulties, and Future Directions 335 References 336 13 Aging
of Interpenetrating Polymer Networks 341 Selvin P. Thomas and Mohammed N.
Alghamdi 13.1 Introduction 341 13.2 Aging of Interpenetrating Polymer
Networks 342 13.3 Conclusion 361 References 362 14 Theoretical Modeling and
Simulation of IPNs 365 Prathab Baskar 14.1 Introduction 365 14.2
Theoretical Simulations 366 14.3 Molecular Dynamics Methods and Theory 368
14.4 Molecular Dynamic Study of Surface/Interface Properties of
Thermoplastic Apparent Interpenetrating Polymer Networks and
Organic-Inorganic Composite Interpenetrating Polymer Networks 375 14.5
Conclusions 380 References 380 15 Applications of Interpenetrating Polymer
Networks 383 Radhika Raveendran and Chandra P. Sharma 15.1 Introduction 383
15.2 What are Interpenetrating Polymer Networks? 384 15.3 Properties of
Interpenetrating Polymer Networks 385 15.4 Applications of Interpenetrating
Polymer Networks 385 15.5 Conclusion 393 References 394 Index 399