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The literature presents a systematic study on synthesis, characterization and application of poly (azomethine ester) / polyaniline-HCl blends by analyzing the structural, microstructural, electrical, optical, dielectric and thermal stability properties of the films deposited using solution cast technique. The study of these newly synthesized poly (azomethine ester) / polyaniline-HCl blends prove their potential to find a suitable place in Electronic gadgets, Gas sensors and Thermal detectors.