The author describes the synthesis technique of Ferroelectric Polymer (PVDF) and its composites. The author provides the comprehensive results of characterization of prepares FP composites supported by XRD, SEM and FTIR as well the results on electrical and mechanical properties of the samples. The author has presented interesting results of electrical and magnetically poling effect on dielectric properties. The author has also presented results on gamma irradiation effect on ferroelectric polymer solution.