The author summarizes the development and the applications of overlap determinant method in various fields of pericyclic reactivity. The greatest advantage of this new method lies in its remarkable simplicity and flexibility owing to which it opens an interesting possibility of the systematic investigation of important mechanistic problems of pericyclic reactivity which were so far beyond the scope of other existing techniques.
The author summarizes the development and the applications of overlap determinant method in various fields of pericyclic reactivity. The greatest advantage of this new method lies in its remarkable simplicity and flexibility owing to which it opens an interesting possibility of the systematic investigation of important mechanistic problems of pericyclic reactivity which were so far beyond the scope of other existing techniques.
The book is written primarily for students and active research workers in the field of theoretical and physical organic chemistry, who favour the possibility to predict the preferred reaction mechanism or the eventual substituent induced violation of Woodward-Hoffmann rules.
Inhaltsangabe
From the contents: Introduction.- Pericyclic Reactions.- Woodward-Hoffmann Rules.- Frontier Orbital Theory.- Overlap Determinant Method.- Least Motion Principle.- Mechanisms of Pericyclic Reactions.- Miscellaneous.- Appendix.- Future Perspectives.
From the contents: Introduction.- Pericyclic Reactions.- Woodward-Hoffmann Rules.- Frontier Orbital Theory.- Overlap Determinant Method.- Least Motion Principle.- Mechanisms of Pericyclic Reactions.- Miscellaneous.- Appendix.- Future Perspectives.
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