Scientific and technological advancements have played a pivotal role in satisfying the needs of our developing society. This technological endeavor demands improvisation on the materials. Hence the perovskite structure has attracted a lot of attention. Lanthanum Titanate is a prominent member of the perovskite family. On par with M-O bonds are observing in this ABO3 type of perovskite structure compounds. With that the electrical behavior also carried out in the manner of synthesized samples. These Lanthanum Titanate nanoparticles are prepared through different techniques such as sol-gel, solid state reaction methods etc. By doping various transition materials within the perovskite structure, the properties of the La-based substances can be increased. AlxLa1-xTiO3 (x = 0.2, 0.4, 0.6 and 0.8), Al0.8 EuxLa0.2-xTiO3 (x = 0.2, 0.4, 0.6 and 0.8) and Al0.8GdyLa0.2-yTiO3 (y = 0.01, 0.02, 0.03 and 0.04) nanostructures are prepared using hydrothermal technique for Structural, Morphological, Optical, and Dielectric Properties. Finally, these materials are suitable applications for high charge stored capacitors, sensors, and optoelectronic devices.